| Novak Djokovic (1) | Bye | | | | | | |
| Bye | - | Novak Djokovic (1) | 6, 6 | | | | |
| Bernard Tomic | 4, 6, 6 | Bernard Tomic | 3, 3 | | | | |
| Santiago Giraldo | 6, 2, 4 | | | Novak Djokovic (1) | 4, 6, 6 | | |
| Radek Stepanek | 2, 6, 6 | | | Juan Monaco (14) | 6, 2, 3 | | |
| Juan Ignacio Chela | 6, 0, 3 | Radek Stepanek | 4, 2 | | | | |
| Adrian Ungur | 2, 2 | Juan Monaco (14) | 6, 6 | | | | |
| Juan Monaco (14) | 6, 6 | | | | | Novak Djokovic (1) | 7, 6 |
| Juan Martin Del Potro (10) | 7, 3, 6 | | | | | Jo-Wilfried Tsonga (5) | 5, 1 |
| Michael Llodra | 5, 6, 4 | Juan Martin Del Potro (10) | 6, 6 | | | | |
| Thomaz Bellucci | 2, 6, 3 | Mikhail Youzhny | 4, 2 | | | | |
| Mikhail Youzhny | 6, 3, 6 | | | Juan Martin Del Potro (10) | 4, 1 | | |
| Viktor Troicki | 4, 6, 6 | | | Jo-Wilfried Tsonga (5) | 6, 6 | | |
| Filippo Volandri | 6, 4, 3 | Viktor Troicki | 3, 2 | | | | |
| Bye | - | Jo-Wilfried Tsonga (5) | 6, 6 | | | | |
| Jo-Wilfried Tsonga (5) | Bye | | | | | | |
| Roger Federer (3) | Bye | | | | | | |
| Bye | - | Roger Federer (3) | 6, 6 | | | | |
| Blaz Kavcic | 1, 3 | Carlos Berlocq | 3, 4 | | | | |
| Carlos Berlocq | 6, 6 | | | Roger Federer (3) | 6, 5, 6 | | |
| Kevin Anderson | 4, 5 | | | Juan Carlos Ferrero | 2, 7, 1 | | |
| Juan Carlos Ferrero | 6, 7 | Juan Carlos Ferrero | 7, 6 | | | | |
| Alex Bogomolov Jr. | 4, 1 | Gael Monfils (13) | 5, 3 | | | | |
| Gael Monfils (13) | 6, 6 | | | | | Roger Federer (3) | 6, 6 |
| John Isner (9) | 2, 7 (7), 6 | | | | | Andreas Seppi | 1, 2 |
| Philipp Kohlschreiber | 6, 6 (6), 2 | John Isner (9) | 6, 6 (5), 5 | | | | |
| Andreas Seppi | 6, 3, 6 | Andreas Seppi | 2, 7 (7), 7 | | | | |
| Denis Istomin | 4, 6, 3 | | | Andreas Seppi | 6 (1), 7 (8), 7 (8) | | |
| Stan Wawrinka | 6, 4, 7 | | | Stan Wawrinka | 7 (7), 6 (6), 6 (6) | | |
| Robin Haase | 1, 6, 5 | Stan Wawrinka | 6, 6 | | | | |
| Bye | - | Janko Tipsarevic (8) | 3, 1 | | | | |
| Janko Tipsarevic (8) | Bye | | | | | | |
| David Ferrer (6) | Bye | | | | | | |
| Bye | - | David Ferrer (6) | 6, 7 (7) | | | | |
| Fernando Verdasco | 6 | Fernando Verdasco | 3, 6 (3) | | | | |
| Alexandr Dolgopolov | 0 retired | | | David Ferrer (6) | 6, 7 (7) | | |
| Guillermo Garcia-Lopez | 6, 6 | | | Gilles Simon (11) | 0, 6 (4) | | |
| Pablo Andujar | 4, 1 | Guillermo Garcia-Lopez | 4, 6, 4 | | | | |
| Donald Young | 2, 5 | Gilles Simon (11) | 6, 2, 6 | | | | |
| Gilles Simon (11) | 6, 7 | | | | | David Ferrer (6) | 7 (7), 6 |
| Richard Gasquet (16) | 6, 7 (8) | | | | | Richard Gasquet (16) | 6 (4), 3 |
| Jurgen Melzer | 1, 6 (6) | Richard Gasquet (16) | 6, 6 | | | | |
| Nikolay Davydenko | 3, 6, 3 | Paolo Lorenzi | 3, 2 | | | | |
| Paolo Lorenzi | 6, 2, 6 | | | Richard Gasquet (16) | 6 (1), 6, 6 | | |
| Albert Ramos-Vinolas | 3, 4 | | | Andy Murray (4) | 7 (7), 3, 2 | | |
| David Nalbandian | 6, 6 | David Nalbandian | 1, 6, 5 | | | | |
| Bye | - | Andy Murray (4) | 6, 4, 7 | | | | |
| Andy Murray (4) | Bye | | | | | | |
| Tomas Berdych (7) | Bye | | | | | | |
| Bye | - | Tomas Berdych (7) | 6, 6 | | | | |
| Lukasz Kubot | 6, 5, 6 | Lukasz Kubot | 4, 1 | | | | |
| Potito Starace | 3, 7, 2 | | | Tomas Berdych (7) | 7 (7), 6 | | |
| Sam Querrey | 7 (7), 5, 6 | | | Nicolas Almagro (12) | 6 (3), 3 | | |
| Jarkko Nieminen | 6 (4), 7, 4 | Sam Querrey | 5, 2 | | | | |
| Marin Cilic | 2, 6, 0 | Nicolas Almagro (12) | 7, 6 | | | | |
| Nicolas Almagro (12) | 6, 3, 6 | | | | | Tomas Berdych (7) | 4, 5 |
| Feliciano Lopez (15) | 4, 4 | | | | | Rafael Nadal (2) | 6, 7 |
| Marcel Granollers | 6, 6 | Marcel Granollers | 6, 6 | | | | |
| Fabio Fognini | 6, 6 | Fabio Fognini | 3, 4 | | | | |
| Marcos Baghdatis | 2, 2 | | | Marcel Granollers | 1, 1 | | |
| Milos Raonic | 6 (5), 4 | | | Rafael Nadal (2) | 6, 6 | | |
| Florian Mayer | 7 (7), 6 | Florian Mayer | 1, 5 | | | | |
| Bye | - | Rafael Nadal (2) | 6, 7 | | | | |
| Rafael Nadal (2) | Bye | | | | | | |
