| Novak Djokovic (1) | Bye | | | | | | |
| Bye | - | Novak Djokovic (1) | 6, 6 | | | | |
| Leonardo Mayer | 1, 4 | Marcos Baghdatis | 4, 4 | | | | |
| Marcos Baghdatis | 6, 6 | | | Novak Djokovic (1) | 6, 6 | | |
| Guillermo Garcia-Lopez | 6, 7 (9) | | | Viktor Troicki (27) | 3, 4 | | |
| Rajeev Ram | 4, 6 (7) | Guillermo Garcia-Lopez | 6, 1, 4 | | | | |
| Bye | - | Viktor Troicki (27) | 4, 6, 6 | | | | |
| Viktor Troicki (27) | Bye | | | | | Novak Djokovic (1) | 7, 6 |
| Richard Gasquet (17) | Bye | | | | | Richard Gasquet (17) | 5, 3 |
| Bye | - | Richard Gasquet (17) | 6, 6 (6), 6 | | | | |
| Cedrik-Marcel Stebe | 6, 7 | Cedrik-Marcel Stebe | 3, 7 (8), 2 | | | | |
| Flavio Cipolla | 3, 5 | | | Richard Gasquet (17) | 6, 5, 6 | | |
| Albert Ramos-Vinolas | 6, 6 | | | Albert Ramos-Vinolas | 2, 7, 3 | | |
| Simone Bolelli | 3, 1 | Albert Ramos-Vinolas | 6, 7 (7) | | | | |
| Bye | - | Feliciano Lopez (15) | 4, 6 (5) | | | | |
| Feliciano Lopez (15) | Bye | | | | | | |
| Juan Martin Del Potro (11) | Bye | | | | | | |
| Bye | - | Juan Martin Del Potro (11) | 7, 6 | | | | |
| Lukasz Kubot | 3, 7 (7), 6 (2) | Ivo Karlovic | 5, 4 | | | | |
| Ivo Karlovic | 6, 6 (2), 7 (7) | | | Juan Martin Del Potro (11) | 6, 7 (7) | | |
| Igor Kunitsyn | 7 (10), 7 (7) | | | Marin Cilic (23) | 3, 6 (3) | | |
| Jesse Levine | 6 (8), 6 (3) | Igor Kunitsyn | 3, 6 (1) | | | | |
| Bye | - | Marin Cilic (23) | 6, 7 (7) | | | | |
| Marin Cilic (23) | Bye | | | | | Juan Martin Del Potro (11) | 3, 3 |
| Julien Benneteau (30) | Bye | | | | | David Ferrer (5) | 6, 6 |
| Bye | - | Julien Benneteau (30) | 3, 6, 7 (7) | | | | |
| Benjamin Becker | 5, 6, 6 | Benjamin Becker | 6, 3, 6 (4) | | | | |
| Olivier Rochus | 7, 3, 2 | | | Julien Benneteau (30) | 6 (5), 4 | | |
| Sergiy Stakhovsky | 6 (4), 3 | | | David Ferrer (5) | 7 (7), 6 | | |
| Bernard Tomic | 7 (7), 6 | Bernard Tomic | 4, 4 | | | | |
| Bye | - | David Ferrer (5) | 6, 6 | | | | |
| David Ferrer (5) | Bye | | | | | | |
| Roger Federer (3) | Bye | | | | | | |
| Bye | - | Roger Federer (3) | 6, 7 (7) | | | | |
| Ryan Harrison | 6 (6), 6, 6 | Ryan Harrison | 2, 6 (3) | | | | |
| Potito Starace | 7 (8), 4, 4 | | | Roger Federer (3) | 6 (4), 6, 4 | | |
| Alex Bogomolov Jr. | 7, 4, 6 (5) | | | Andy Roddick (31) | 7 (7), 1, 6 | | |
| Gilles Muller | 5, 6, 7 (7) | Gilles Muller | 3, 2 | | | | |
| Bye | - | Andy Roddick (31) | 6, 6 | | | | |
| Andy Roddick (31) | Bye | | | | | Andy Roddick (31) | 5, 0 |
| Juan Monaco (21) | Bye | | | | | Juan Monaco (21) | 7, 6 |
| Bye | - | Juan Monaco (21) | 5 | | | | |
| Yen-Hsun Lu | 6, 6 | Yen-Hsun Lu | 0 retired | | | | |
| Jarkko Nieminen | 4, 3 | | | Juan Monaco (21) | 4, 6, 6 | | |
| Sergei Bubka | 6, 6 | | | Gael Monfils (14) | 6, 3, 4 | | |
| Ernests Gulbis | 4, 4 | Sergei Bubka | 4, 4 | | | | |
| Bye | - | Gael Monfils (14) | 6, 6 | | | | |
| Gael Monfils (14) | Bye | | | | | | |
| Nicolas Almagro (12) | Bye | | | | | | |
| Bye | - | Nicolas Almagro (12) | 6, 6 | | | | |
| David Goffin | 7, 6 | David Goffin | 4, 2 | | | | |
| Donald Young | 5, 4 | | | Nicolas Almagro (12) | 6, 6 | | |
| Bjorn Phau | 6, 6 | | | Fernando Verdasco (20) | 3, 4 | | |
| Carlos Berlocq | 4, 2 | Bjorn Phau | 3, 0 | | | | |
| Bye | - | Fernando Verdasco (20) | 6, 6 | | | | |
| Fernando Verdasco (20) | Bye | | | | | Nicolas Almagro (12) | 3, 7 (7), 3 |
| Kevin Anderson (28) | Bye | | | | | Mardy Fish (8) | 6, 6 (2), 6 |
| Bye | - | Kevin Anderson (28) | 6, 6 (3), 6 | | | | |
| Sam Querrey | 6, 5, 7 | Sam Querrey | 3, 7 (7), 3 | | | | |
| Matthew Ebden | 1, 7, 5 | | | Kevin Anderson (28) | 4, 3 | | |
| Frank Dancevic | 7, 7 (7) | | | Mardy Fish (8) | 6, 6 | | |
| Jeremy Chardy | 5, 6 (0) | Frank Dancevic | 3, 6 (1) | | | | |
| Bye | - | Mardy Fish (8) | 6, 7 (7) | | | | |
| Mardy Fish (8) | Bye | | | | | | |
| Tomas Berdych (7) | Bye | | | | | | |
| Bye | - | Tomas Berdych (7) | 7, 6 | | | | |
| Nicolas Mahut | 7, 4, 7 (7) | Nicolas Mahut | 5, 1 | | | | |
| Fernando Gonzalez | 5, 6, 6 (3) | | | Tomas Berdych (7) | 3, 6, 4 | | |
| Grigor Dimitrov | 6, 6 | | | Grigor Dimitrov | 6, 2, 6 | | |
| Mikhail Kukushkin | 2, 2 | Grigor Dimitrov | 6, 4, 6 | | | | |
| Bye | - | Juan Ignacio Chela (29) | 2, 6, 4 | | | | |
| Juan Ignacio Chela (29) | Bye | | | | | Grigor Dimitrov | 6 (3), 2 |
| Alexandr Dolgopolov (18) | Bye | | | | | Janko Tipsarevic (9) | 7 (7), 6 |
| Bye | - | Alexandr Dolgopolov (18) | 6, 7 | | | | |
| Antonio Veic | 2, 6, 6 | Antonio Veic | 4, 5 | | | | |
| Denis Kudla | 6, 2, 1 | | | Alexandr Dolgopolov (18) | 4, 7, 2 | | |
| David Nalbandian | 6, 7 (7) | | | Janko Tipsarevic (9) | 6, 5, 6 | | |
| Steve Darcis | 4, 6 (0) | David Nalbandian | 5, 3 | | | | |
| Bye | - | Janko Tipsarevic (9) | 7, 6 | | | | |
| Janko Tipsarevic (9) | Bye | | | | | | |
| Gilles Simon (13) | Bye | | | | | | |
| Bye | - | Gilles Simon (13) | 6, 6 | | | | |
| Roberto Bautista Agut | 6, 1, 6 | Roberto Bautista Agut | 4, 2 | | | | |
| Andreas Seppi | 3, 6, 3 | | | Gilles Simon (13) | 7 (7), 6 | | |
| Robin Haase | 6, 6 | | | Jurgen Melzer (22) | 6 (5), 4 | | |
| Marinko Matosevic | 3, 4 | Robin Haase | 6 (2), 6, 4 | | | | |
| Bye | - | Jurgen Melzer (22) | 7 (7), 3, 6 | | | | |
| Jurgen Melzer (22) | Bye | | | | | Gilles Simon (13) | 3, 4 |
| Milos Raonic (26) | Bye | | | | | Andy Murray (4) | 6, 6 |
| Bye | - | Milos Raonic (26) | 7 (9), 6 | | | | |
| Dudi Sela | 3, 3 | Arnaud Clement | 6 (7), 2 | | | | |
| Arnaud Clement | 6, 6 | | | Milos Raonic (26) | | | |
| Alejandro Falla | 6, 2 | | | Andy Murray (4) | walk-over | | |
| Denis Istomin | 1, 1 retired | Alejandro Falla | 2, 3 | | | | |
| Bye | - | Andy Murray (4) | 6, 6 | | | | |
| Andy Murray (4) | Bye | | | | | | |
| Jo-Wilfried Tsonga (6) | Bye | | | | | | |
| Bye | - | Jo-Wilfried Tsonga (6) | 7, 7 | | | | |
| Edouard Roger-Vasselin | 6 (3), 3 | Xavier Malisse | 5, 5 | | | | |
| Xavier Malisse | 7 (7), 6 | | | Jo-Wilfried Tsonga (6) | 6, 7 (7) | | |
| Thomaz Bellucci | 3, 4 | | | Philipp Kohlschreiber (32) | 4, 6 (2) | | |
| Frederico Gil | 6, 6 | Frederico Gil | 2, 5 | | | | |
| Bye | - | Philipp Kohlschreiber (32) | 6, 7 | | | | |
| Philipp Kohlschreiber (32) | Bye | | | | | Jo-Wilfried Tsonga (6) | 6, 6 |
| Florian Mayer (19) | Bye | | | | | Florian Mayer (19) | 3, 2 |
| Bye | - | Florian Mayer (19) | 6, 7 | | | | |
| Philipp Petzschner | 0, 6, 6 (5) | Ivan Dodig | 4, 5 | | | | |
| Ivan Dodig | 6, 2, 7 (7) | | | Florian Mayer (19) | 6, 6 | | |
| Nikolay Davydenko | 4, 6, 6 | | | John Isner (10) | 4, 2 | | |
| James Blake | 6, 4, 4 | Nikolay Davydenko | 6, 3, 4 | | | | |
| Bye | - | John Isner (10) | 2, 6, 6 | | | | |
| John Isner (10) | Bye | | | | | | |
| Kei Nishikori (16) | Bye | | | | | | |
| Bye | - | Kei Nishikori (16) | 6, 6 | | | | |
| Ryan Sweeting | 4, 4 | Lukas Lacko | 3, 3 | | | | |
| Lukas Lacko | 6, 6 | | | Kei Nishikori (16) | 6, 6 | | |
| Michael Llodra | 4, 6 (6) | | | Lukas Rosol | 4, 2 | | |
| Lukas Rosol | 6, 7 (8) | Lukas Rosol | 2, 6, 6 | | | | |
| Bye | - | Marcel Granollers (24) | 6, 3, 1 | | | | |
| Marcel Granollers (24) | Bye | | | | | Kei Nishikori (16) | 4, 4 |
| Radek Stepanek (25) | Bye | | | | | Rafael Nadal (2) | 6, 6 |
| Bye | - | Radek Stepanek (25) | 7 (7), 6 | | | | |
| Guillaume Rufin | 4, 4 | Tommy Haas | 6 (4), 1 | | | | |
| Tommy Haas | 6, 6 | | | Radek Stepanek (25) | 2, 2 | | |
| Pablo Andujar | 3, 2 | | | Rafael Nadal (2) | 6, 6 | | |
| Santiago Giraldo | 6, 6 | Santiago Giraldo | 2, 0 | | | | |
| Bye | - | Rafael Nadal (2) | 6, 6 | | | | |
| Rafael Nadal (2) | Bye | | | | | | |
